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Definitely One of the most importance comics in all of Batman was introduced in 71' Batman 232 Daughter of the Demon.
Done by Neal Adams and Dennis O'neil
This was the first appearance and creation of Ra's Al Ghoul!!!!!
This book introduces Talia, Ra's, League of Assassins and eventually spawns Damian Wayne the latest Robin.
Also during this time Batman is started to be considered a more serious character and Batman was breaking away from his silver age/ Batman 66' self. The 70's was defiantly a significant period for the Batman Comics!!
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